Electronic structure methods for complex chemical systems ACS Division of Physical Chemistry 254th National ACS Meeting August 20-24, 2017, Washington DC Organisers: James J. Shepherd, MIT Sahar Sharifzadeh, BU Filipp Furche, UC Irvine Electronic structure methods are providing insight into complex chemical systems with a scope and realism unimaginable just a few years ago. For example, transition states involving large and complex substrates with a multitude of interactions can now be modeled without truncation; interaction of light with materials, reactions at interfaces, and heterogeneous catalysis can be studied using predictive many-body methods; and weak interactions of nanosystems and soft matter can increasingly be investigated with correlated wavefunction methods. This symposium will highlight the latest developments in electronic structure theory and examine their impact on modeling of complex chemical systems. Topics will include emerging directions, correlated electronic structure methods, noncovalent interactions, nanosystems, and solvation, ultra-efficient electronic structure methods and molecular dynamics, many-body perturbation theory, random phase approximation methods, and electronic structure of extended systems. We aim to bring together scientists with diverse backgrounds and foster discussion and exchange of ideas beyond the traditional boundaries of the physics, chemistry, materials and computational science communities. Contributed papers by students and post-doctoral scholars are welcome. On-line abstract submission deadline is 06 April, 2017. Click here to submit your abstract. Schedule Location: Walter E. Washington Convention Center Room: Room 151A Session: Many-body Perturbation Theory, Random Phase Approximation & Beyond Presider: Brenda Rubenstein Time: 8:00 AM - 12:00 PM Date: Sun, Aug 20 8:00 AM-8:05 AM Filipp Furche Introductory Remarks 8:05 AM-8:30 AM Steven Louie Excited-state phenomena in condensed matter: GW, GW-BSE, and beyond 8:30 AM-8:55 AM Johannes Lischner Electronic excitations at solid-liquid interfaces 8:55 AM-9:10 AM Arindam Chakraborty Real-space representation of electron-hole interaction kernel in excitonic systems 9:10 AM-9:20 AM Intermission 9:20 AM-9:45 AM Noa Marom Effect of crystal packing on the electronic properties of molecular crystals 9:45 AM-10:00 AM Xiaopeng Wang Effect of crystal packing on the excitonic properties of rubrene polymorphs 10:00 AM-10:15 AM Kirk Lewis The optical properties of stilbene from first-principles 10:15 AM-10:40 AM Adrienn Ruzsinszky Beyond RPA: Kernels and renormalization 10:40 AM-10:55 AM Jefferson Bates Convergence behavior of RPA renormalized many-body perturbation theory and applications to periodic systems 10:55 AM-11:05 AM Intermission 11:05 AM-11:30 AM Dominika Zgid Self-consistent temperature dependent Green's function methods applied to solids and molecules 11:30 AM-11:45 AM Alexei Kananenka Combining density functional theory and Green's function theory: Range-separated, non-local, dynamic hybrid functional 11:45 AM-12:00 PM Lan Tran Towards rigorous ab initio quantum embedding for realistic systems in the framework of Green's function theory Session: Extended Systems Presider: Johannes Lischner Time: 1:00 PM - 5:00 PM Date: Sun, Aug 20 1:00 PM-1:25 PM Sivan Refaely-Abramson Single- and multi-exciton phenomena in organic systems from first principles 1:25 PM-1:40 PM Withdrawn 1:40 PM-1:55 PM Niranjan Ilawe Unraveling excitation energy transfer mechanisms in plasmonic nanoantennas 1:55 PM-2:20 PM Eran Rabani Stochastic electronic strcture methods: Improving scaling by introducing a controlled statistical error 2:20 PM-2:35 PM Joanna Jankowska Probing the mechanism of tip-molecule charge transfer in the STM setup: A non-adiabatic molecular dynamics study 2:35 PM-2:45 PM Intermission 2:45 PM-3:10 PM Brenda Rubenstein High-accuracy trial wave functions on the cheap: Stochastic variational algorithms for quantum chemistry 3:10 PM-3:25 PM Joshua Kretchmer Fully quantum simulation of surface enhanced Raman scattering from real-time ab-initio methods 3:25 PM-3:40 PM Sarah Allec GPU-enabled real-time electron dynamics of nitrogen-doped graphene nanoflakes 3:40 PM-3:50 PM Intermission 3:50 PM-4:15 PM Andreas Grüneis Finite size corrections in coupled cluster theory calculations of solids and surfaces 4:15 PM-4:30 PM Chen Huang Random phase approximation calculations based on patching exchange-correlation potential 4:30 PM-4:45 PM Withdrawn 4:45 PM-5:00 PM Alexander Rusakov Finite-temperature second-order Green's function approach to electronic correlations in solids Session: Noncolvalent Interactions, Nanosystems & Solvation Presider: Garnet Chan Time: 8:00 AM - 12:00 PM Date: Mon, Aug 21 8:00 AM-8:25 AM John Herbert First-principles exciton models, with application to singlet fission 8:25 AM-8:40 AM Mohammad R. Momeni Unravelling singlet fission mechanism in quinoidal systems 8:40 AM-8:55 AM Zhou Lin Photochemical dynamics for intramolecular singlet fission in covalently-bound pentacene dimers 8:55 AM-9:10 AM Rachel Krueger Equilibrium geometries and binding energy scaling relationships for aromatic excimers and exciplexes: A TDDFT and NEVPT2 study 9:10 PM-9:20 PM Intermission 9:20 AM-9:45 AM Peihong Zhang Fully converged GW quasiparticle calculations for large systems 9:45 AM-10:10 AM David Strubbe Excited-state forces in TDDFT and the Bethe-Salpeter equation 10:10 AM-10:25 AM Meng Zhou Evolution from the plasmon to exciton state in atomically precise gold nanoparticles 10:25 AM-10:40 AM Susan Atlas Dressed atom design of charge-transfer force fields 10:40 AM-10:50 AM Intermission 10:50 AM-11:15 AM Steven Wheeler Computational design of asymmetric organocatalysts 11:15 AM-11:30 AM Christoph Bannwarth Simplified methods for the computation of electronic absorption and circular dichroism spectra 11:30 AM-11:45 AM Withdrawn 11:45 AM-12:00 PM Lisa Fredin Unique electronic structure of iron carbene photosensitizers Session: Emerging Directions in Electronic Structure Presider: Francesco Evangelista Time: 1:00 PM - 5:00 PM Date: Mon, Aug 21 1:00 PM-1:25 PM E.K.U. Gross Potential energy surfaces and Berry phases beyond the Born-Oppenheimer approximation 1:25 PM-1:40 PM Vojtech Vlcek Quasiparticle spectra from stochastic many-body methods 1:40 PM-1:55 PM Stefan Vuckovic Exchange-correlation functionals for chemical applications from the strong-coupling limit of DFT 1:55 PM-2:10 PM Petr Slavicek Beyond Koopmans: Modelling ionization energies in solution 2:10 PM-2:20 PM Intermission 2:20 PM-2:45 PM Eric Neuscamman Progress in excited state variational principles for molecules and solids 2:45 PM-3:10 PM Takashi Tsuchimochi Correlated electronic structure methods based on spin-projection for open-shell systems 3:10 PM-3:25 PM Matthias Degroote Symmetry breaking and restoration by similarity transformation 3:15 PM-3:25 PM Intermission 3:35 PM-4:00 PM Garnet Chan Quantum embedding for complex systems 4:00 PM-4:15 PM Dhabih Chulhai Projection-based quantum embedding for molecular and periodic systems 4:15 PM-4:30 PM Yuki Sakai Simulation of atomic force microscopy with density embedding theory and its implementation to realspace DFT code PARSEC 4:30 PM-4:45 PM Kurt Brorsen Colle-Salvetti based functional for the inclusion of electron-proton correlation in multicomponent density functional theory 4:45 PM-5:00 PM Nadav Geva Machine learning acceleration of non-local density functionl theory Session: Correlated Electronic Structure Methods for Complex Systems Presider: Eric Neuscamman Time: 8:00 AM - 11:35 PM Date: Tue, Aug 22 8:00 AM-8:25 AM Piotr Piecuch Single-reference coupled-cluster and equation-of-motion coupled-cluster methods for multi-reference problems: CC(P;Q) formalism 8:25 AM-8:50 AM Francesco Evangelista Electron correlation methods for near-degenerate states based on the driven similarity renormalization group 8:50 AM-9:05 AM John Gomez Attenuated coupled cluster: A novel single-reference approach for strongly correlated systems 9:05 AM-9:20 AM Chong Peng Extending the reach of the CCSD(T) method by massive parallelism and reduced scaling 9:20 PM-9:30 PM Intermission 9:30 AM-9:45 AM Paul Zimmerman Correlation energies through incremental full configuration interaction 9:45 AM-10:00 AM Aaron West Truncating the configuration interaction (CI) expansion through modified orthogonalization of molecular orbitals 10:00 AM-10:15 AM Sandra Varinia Bernales Candia Multiconfiguration quantum embedding methods 10:15 AM-10:30 AM Frederic Gendron Multi-reference calculations of NMR shifts in open-shell actinide complexes 10:30 PM-10:40 PM Intermission 10:40 AM-11:05 AM So Hirata One-particle many-body Green's function theory: Algebraic recursions, linked-diagram and irreducible-diagram theorems, and general-order algorithms 11:05 AM-11:20 AM William Witt Orbital-free density functional theory with atom-centered density matrices 11:20 AM-11:35 AM Nicholas Blunt Charge transfer excited states: A balanced and efficient wave function ansatz in variational Monte Carlo 11:35 AM-12:00 PM Ed Valeev Reduced scaling many-body methods in non-LCAO representations Session: Ultra-efficient Electronic Structure Methods & Molecular Dynamics Presider: Sivan Refaely-Abramson Time: 1:00 PM - 4:50 PM Date: Tue, Aug 22 1:00 PM-1:25 PM Sergei Tretiak Coherent exciton-vibrational dynamics and energy transfer in conjugated organics 1:25 PM-1:40 PM Anthony Dutoi Exciton coupled-cluster theory for large-scale electronic structure calculations: Test application on Ben clusters 1:40 PM-2:05 PM Christine Isborn Modeling excited states in the condensed phase 2:05 PM-2:20 PM Daniel Lambrecht First-principles derived descriptors for linear response properties 2:20 PM-2:30 PM Intermission 2:30 PM-2:55 PM Aiichiro Nakano Computational synthesis and characterization by large quantum and reactive molecular dynamics simulations 2:55 PM-3:10 PM Roland Lindh Non-adabatic dynamics of the 1,2-dioxetane chemiluminescence 3:10 PM-3:25 PM Gregory Medders Accelerating the simulation of nonadiabatic dynamics through an efficient augmented surface hopping algorithm in Q-Chem 3:25 PM-3:35 PM Intermission 3:35 PM-4:00 PM Eric Polizzi Scalable algorithms for real-space and real-time first-principle calculations 4:00 PM-4:15 PM Wei Hu Interpolative separable density fitting decomposition for accelerating large-scale hybrid functional calculations 4:15 PM-4:30 PM Xing Zhang Density-to-potential inversions in density functional theory with atom-centered bases and multiwavelet bases 4:30 PM-4:45 PM G Martyna Projector augmented wave based Kohn-Sham density functional theory simulations with reduced order scaling 4:45 PM-4:50 PM James Shepherd Closing Remarks